National High Technology Research and Development Program of China (863 Program) (No. 2012AA101808), National Natural Science Foundation of China (Nos. 51276103, 510060605).
Fast pyrolysis experiments of corn stalk were performed to investigate the optimal pyrolysis conditions of temperature and bed material for maximum bio-oil production under flue gas atmosphere. Under the optimized pyrolysis conditions, furfural residue, xylose residue and kelp seaweed were pyrolyzed to examine their yield distributions of products, and the physical characteristics of bio-oil were studied. The best flow rate of the flue gas at selected temperature is obtained, and the pyrolysis temperature at 500 °C and dolomite as bed material could give a maximum bio-oil yield. The highest bio-oil yield of 43.3% (W/W) was achieved from corn stalk under the optimal conditions. Two main fractions were recovered from the stratified bio-oils: light oils and heavy oils. The physical properties of heavy oils from all feedstocks varied little. The calorific values of heavy oils were much higher than that of light oils. The pyrolysis gas could be used as a gaseous fuel due to a relatively high calorific value of 6.5?8.5 MJ/m3.
李宁,王祥,柏雪源,李志合,张英. 热烟气气氛下生物质在流化床反应器中快速热解制取生物油[J]. Chinese Journal of Biotechnology, 2015, 31(10): 1501-1511
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