中试厌氧氨氧化反应器的启动与调控

Start-up and process control of a pilot-scale Anammox bioreactor at ambient temperature

摘要:

研究了中试厌氧氨氧化(Anaerobic ammonium oxidation, Anammox)反应器的启动性能。结果表明, 以硝化反硝化污泥、短程硝化污泥、厌氧絮体污泥和厌氧颗粒污泥混合接种, 经过255 d的运行, 可在常温下（5 oC~27 oC）成功启动中试Anammox反应器, 反应器的基质氮去除速率可达1.30 kg/(m3·d)。厌氧氨氧化是致碱反应, 厌氧氨氧化成为反应器内的主导反应后, 进水pH宜控制在厌氧氨氧化适宜范围的偏低水平(6.8左右)。亚硝酸盐既是Anammox菌的基质, 也是抑制剂, 控制进水亚硝酸盐浓度（13~36 mg/L）有助于厌氧氨氧化反应。菌种是生物反应器的功能之源, 向中试装置投加少量厌氧氨氧化污泥(投加比2%), 可大大加速中试Anammox反应器的启动进程。

Abstract:

Start-up and process control of a pilot-scale anaerobic ammonium-oxidizing (Anammox) bioreactor were studied at ambient temperature. Inoculated with a mixture of nitrification-denitrification sludge, nitritation sludge, anaerobic floc sludge and anaerobic granular sludge, the pilot-scale Anammox bioreactor was successfully started up within 255 days at 5oC ?27oC. The nitrogen removal rate reached 1.30 kg/(m3·d). Three facets were taken into account to facilitate the process initiation. First, in terms of alkalization in Anammox, influent pH was kept at about 6.8. Besides, nitrite concentration was kept as low as 13?36 mg/L. Finally, 2% (volumetric ratio) of Anammox sludge from lab-scale bioreactors was supplemented to the pilot-scale one.